The libxml extension is enabled by default, although it may be disabled with --disable-libxml.
   The optional --with-libxml-dir
   directive is used to specify the location of libxml
   on the system that PHP is being compiled on, otherwise only the
   default locations are scanned. The configure process
   checks for libxml (specifically, xml2-config) in the
   following order:
  
The location ([DIR]) specified with --with-libxml-dir ([DIR]=/bin/xml2-config)
/usr/local/bin/xml2-config
/usr/bin/xml2-config
   If configure cannot find xml2-config in the directory
   specified by --with-libxml-dir, then
   it'll continue on and check the default locations.